Chloride stress corrosion cracking in austenitic stainless steel. At 50c they can withstand about 100 ppm of chlorides. It is difficult to control the temperature, while changing pipe material or eliminating residual stresses associated with welding and forming the pipework is costly and incurs plant downtime. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. Is there anything you can do to 316 stainless steel to make it acceptable for use in a chloride environment, or is it just recomended to avoid 316 stainless steel in this application. The environmental factors that increase the cracking susceptibility include higher temperatures, increased chloride content, lower ph, and higher levels of tensile stress.
Stress corrosion cracking of stainless steels in swimming pool buildings. Corrosion of 316 stainless steel tubing has been observed in offshore applications around the world. Duplex stainless steel summary benefits compared to common stainless steels. If you you have temperatures above 150f,you could have stress corrosion cracking of 316 although unlikely below 200 f. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic. Housings and frames can be furnished in all stainless steel, aluminum or monel.
Corrosion behaviour of type 316l stainless steel in hot. Fatigue cracking of a 316l stainless steel nozzle sleeve from a chemical processing vessel. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. As a dry gas it does not tend to be aggressive towards stainless steel, but as either a damp gas or dissolved in water it can be a corrosion hazard. If this is a potable water as described,there is no reason to consider anything but carbon or galvanized steel. What are the effects of chlorides and fluorides on 316 stainless steel.
Scc and pitting corrosion of stainless steels in solutions of halides other than chlorides. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. When stainless steels are fully immersed, it is rare to see chloride stress corrosion cracking at temperatures below 60 c 150 f. It can be concluded that the formation of the pits and the presence of stress can lead to clscc. What is temperature it is more important than concentration of chloride and anything higher than room temperature higher is worse. Initiation and propagation of stress corrosion cracking of. Stress corrosion cracking of an austenitic stainless steel in. Corrosion resistance of the austenitic chromiumnickel stainless steels in chemical environments interpreting corrosion test data the quantitative data secured in corrosion tests are often of a very low order of magnitude. With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. As with any additions, thorough dilution around the injection point is important to avoid localised over. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. Referring to the galvanic chart you will note that passivated 316 stainless steel is located nine lines from the bottom and active 316 stainless steel is located thirteen lines from the top.
If you are using stainless steel bolts under tensile stress, in an environment where chlorine corrosion is likely, you should examine the potential for stress corrosion cracking carefully. The hypochlorites, although alkaline, are oxidising. Corrosion products, foulants, microbiological films. Localised corrosion is often associated wuth chloride ions in aqueous environments. Type 316 316l stainless steel with exposure to up to. Type 316 stainless steel in an environment of 25% phosphoric acid, and.
One of new york citys most impressive landmarks is the stainless steel clad peak of the chrysler building. Effect of ph and chloride concentration on the corrosion. Greetings, my name is alex granina and i am a nuclear valve sales engineer working for a flow control division of a corporation. Commercially concentrated sodium hypochlorite is around 15wt %. Guidelines for using stainless steel in the water and desalination. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. Corrosion assisted fatigue cracking of a 316l stainless steel nozzle sleeve from a chemical processing vessel summary.
In marine installations where swagelok 316 316l stainless steel fittings have performed well, but 316 316l tubing has experienced crevice corrosion in tube clamps, it may be costeffective to use 316 316l fittings in combination with tubing from a more corrosion resistant alloy. The rest potential for annealed type 316 stainless steel has been mapped for a wide range of oxygen and chloride content waters and it is shown that at 265c the. Effects of chloride and oxygen on stress corrosion. Typical stress corrosion cracking occurred in all runs of type 304 steel, but slight stress corrosion cracking took place in type 304 l steel only on a run at the interface of air and 1,000 ppm cl. Atmospheric chlorideinduced stress corrosion cracking of types 304 and 316 austenitic stainless steel has been reported at temperatures far below 60uc with exposure to mgcl 2, cacl 2, or. Chlorideinduced stress corrosion cracking of 316 stainless steel oil tube. In this case, the most fashion of failure mode in ss is present.
Therefore, standard grades such as 304304l and 316316l are very. Sour service limits of dualcertified 316316l steel twi. Stainless steels are more resistant to general corrosion compared with carbon steel. Corrosion resistance of austenitic stainless steels ss in artificial seawater containing 0. Corrosion of stainless steel by hot caustic research using solutions of chemically pure caustic sodium hydroxide naoh led to the development of a diagram that attempts to delineate the param eters of concentration and tem perature governing stress corrosion cracking scc of type. Design guidelines for the selection and use of stainless steel nidl distributed by. Corrosion resistant metals materials selection guide swagelok. Together, chlorine and chloride cause stainless steel failures that wouldnt occur by exposure to chlorine or chloride alone. Chloride induced stress corrosion cracking of stainless. It is not recommended to use stainless steel of the type aisi 316 or aisi 316l in stagnant seawater.
Material corrosion resistance guide fluid technology. Chloride corrosion of carbon steel pipe engineering. The chemical composition and mechanical properties of the gauge cover alloy are shown in table 3, table 4, indicating 316 ss stainless steel. The solution can be unstable, giving off chlorine gas. Comparing chemical composition of dark brown corrosion products with that of normal area revealed that the contaminants consisted of sulfur, calcium, potassium, sodium, and chlorine, especially for sulfur and chlorine, the aggressive species that induce stress corrosion cracking in austenitic stainless steel. For 316 stainless steel, also severe atmospheric corrosion and corrosion under insulation may occur.
Are your stainless steel surfaces being corroded by. The hsl research report 902 reference 1 covers the susceptibility of stainless steel to ciscc in some detail and links to other research papers and published documents. Stress corrosion cracking is a general term describing stressed alloy failures appearing as cracks in the stainless steel that occur in corrosive environments. Chloride stress corrosion cracking ssina specialty steel. This provides improved fatigue and wear resistance welding must maintain the duplex structure, especially the. The actual pitting corrosion phenomenon is shown on propeller shaft of high speed craft, and the pit depth was measured with dial.
Corrosion rates of different alloys in dry chlorine and temperature c at which given rates are exceeded are presented in the table below. The duplex stainless steels were developed to exhibit comparable general corrosion resistance as 316ss, but with reduced susceptibility to chloride stress. What are the effects of chlorides and fluorides on 316. Corrosion is a serious development that can lead to perforations of the tubing wall and the escape, under pressure, of highly flammable chemicals. C are not recommended for 304 or 316 as they are at risk of sudden failure from chloride stress corrosion cracking. Cracking of stainless steel nozzle sleeve metallurgical. The tallest manmade monument in the us, the st louis arch, is entirely clad in 304 stainless steel plates.
Stress corrosion cracking of sensitized type 304 stainless. However, as previously mentioned, they are susceptible to local corrosion like pitting corrosion and stress corrosion cracking scc. Guidelines for using stainless steel in the water and. The typical crack morphology for chloride stress corrosion cracking consists of. Effect of dissolved ozone on corrosion behavior of. The presence of chloride in the eds spectrum also confirms the contribution of cl in pitting corrosion of the protective layer of 316 stainless steel plates. When the cor rosion rate is of the order of less than 0.
Effect of chloride deposition on stress corrosion cracking of. Initiation strain for chlorideinduced stress corrosion. Chloride stress corrosion cracking and 316 stainless steel. Localized corrosion and stress corrosion cracking of stainless steels in. Discussion stainless steel there are different types of stainless steel. Localized corrosion and stress corrosion cracking of stainless steels. Effects of chloride and oxygen on stress corrosion cracking of cold worked 316 316l austenitic stainless steel in high temperature water article in corrosion science 110 april 2016 with 117 reads. Corrosion of this type has been extensively studied and affects almost all metal alloys, including the austenitic grades of stainless steel used in brewing. Chloride stress corrosion cracking in austenitic stainless. Selection of stainless steels for handling chlorine. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. Facts in brief about stress corrosion cracking scc stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly. Stainless steels are corrosion resistant, but to take full.
Keep in mind, these concentrations assume no other concentrating mechanism is present. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Scc of the 300 series stainless steels is classically transgranular. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. So the advised materials selection for tubing is 6% mo. It will also break down to oxygen and chlorine, that will ultimately form hydrochloric acid. For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten chocolate in the food industry. The message chlorine and chloride are different forms of the same element but with vastly different effects on stainless steel. Chlorine also has an effect on the degradation of 304 ss and 316 ss. Again, 316ss is more resilient as it is less susceptible to corrosion from chlorine solutions than 304ss, which shows signs of corrosion at 2 ppm of chlorine and 316ss showing signs of corrosion at 4 ppm of chlorine.
This material is susceptible to stress corrosion cracking in sour brines, and thus the use of this material is restricted according to the limits detailed in iso 15156nace mr0175, which are detailed in table 1. Influence of high temperature on corrosion behavior of 304. Pitting and crevice corrosion of offshore stainless steel. Cl2 chlorine is a very potent oxidizer reason it kills bacteria and therefore high levels of chlorine may accelerate chloride corrosion of stainless steels. This article is a primer on stainless steel corrosion and provides recommendations for its best use based on data in. Figure 1 shows the cracking that occurred on a 6mo super austenitic stainless steel n08367 exposed to 0. Selection stainless steel for sodium hypochlorite naocl. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances.
The mineral oil tube failed after being in service for nearly 10 years. This article describes the susceptibility of 316l stainless steel to stress corrosion cracking scc in a nitritecontaining chloride. Stress corrosion cracking british stainless steel association. The micrograph below x300 illustrates scc in a 316 stainless steel chemical processing piping system. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. The stress corrosion cracking of type 316 stainless steel in. If the atmosphere contains halides this can leave any stainless steel susceptible to chloride stress corrosion cracking ciscc. Type 316 stainless steel reaches a maximum critical corrosion rate of.
Hi everybody, today, i would like to show my case study to you. As a general rule, if the wetted parts of the equipment are manufactured from iron, steel, stainless steel or bronze, and they are showing no signs of corrosion, grade 316 stainless is acceptable as long as you do not use stainless steel springs. Corrosion resistance of stainless steels chlorine in contact with water and as a dissolved gas, sometimes found in water treatment applications, is potentially aggressive to stainless steels. According to cyclic polarization data, types 304 ss uns s30400 and 316 ss uns s31600 were resistant to pit initiation after 8 weeks of exposure to ozonated artificial seawater.
This health and safety executive sector information minute sim 5200218 outlines the background to stress corrosion cracking failure hazards to stainless steel items used in indoor swimming poll buildings. The typical crack morphology for chloride stress corrosion cracking consists of branched transgranular cracks. The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress, and sensitization. Stress corrosion cracking facts and how to reduce the. Selection of stainless steel for handling chlorine cl2 and. When using chlorine as a sterilizer or sanitiser in contact with 316 type stainless steel items, a maximum of 1520 ppm mglt free chlorine is suggested, for maximum times of 24 hours, followed by a thorough chlorine free water flush. An introduction to the corrosion resistance of stainless steels. Parkins department of metallurgy and engineering materials, the university, haymarket. Types of corrosion of stainless steels intergranular corroslon when held in the temperature range between 800 and 1650 f, the austenitic stainless steels may undergo a change which renders them susceptible to intergranu lar corrosion upon exposure to a number of corrodents. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern. Stainless steels 304l and 316l exhibit pitting in iodine solutions or solutions. Welded pipes, pipework and components made from the type 316316l grade of austenitic stainless steel are widely used in the oil and gas industry to handle sour fluids i. Scc in a 316 stainless steel chemical processing piping system.
Yes the nace mr 0175 iso 15156 addresses only hydrogen sulfide stress corrosion cracking also called hydrogen stress cracking,and a dozen other names. Built in 1930 of 302 stainless, a recent inspection revealed no signs of corrosion or loss of thickness. Improved corrosion and stress corrosion cracking resistance more resistant to external cracking under insulation higher strength. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. The main benefit of the stainless steels is the corrosion resistivity. I have been reading into stress corrosion cracking scc caused by chlorides, which i understand can be quite an issue. Selection of stainless steels for handling chlorine cl2.
Austenitic steels of type astm 304 and 316 austenitic steels have limited resistance to stress corrosion cracking scc, even at very low chloride contents and temperatures. Olaseinde, comparative study of the effect of temperature on the corrosion behavior of 2205 duplex stainless steel and 316 austenitic stainless steel in acidic chloride environment, advances in materials physics and chemistry 5, 185 190 2015. On the stress corrosion cracking and hydrogen embrittlement. The primary concern in this case is for an insidious form of corrosion called chloride stress corrosion cracking, which gives little indication of crack initiation in very low halide levels, and in the presence of tensile stress. Effect of ph and chloride concentration on the corrosion of. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. A cracked nozzle sleeve stub from a chemical processing vessel of the proprietary vaporizer system was analyzed to determine the cause of cracking. Effect of chloride deposition on stress corrosion cracking of 316l stainless steel used for intermediate level radioactive waste containers. Chloride stress corrosion cracking inspectioneering.
Selection of stainless steel for handling chlorine cl2 and clo2. Effect of chloride deposition on stress corrosion cracking. Nov 01, 2017 for 316 stainless steel, also severe atmospheric corrosion and corrosion under insulation may occur. Is there anything you can do to 316 stainless steel to make it acceptable for use in a chloride environment, or is it just recomended to avoid 316 stainless steel in. Pit type corrosion is therefore simple galvanic corrosion, as the small active area.
The resistance of austenitic stainless steels to scc is related to the nickel content of the. This mode of attack is termed stress corrosion cracking scc. The stress corrosion cracking of type 316 stainless steel. The presence of fe, cr and o can be attributed to the corrosion products of s. It normally occurs as a gas but can be liquefied under pressure at ambient temperature. The combination of tensile stress and a specific corrosive environment can crack stainless steels. Austenitic stainless steels are widely used in manufacturing of the special plates for phe.
Sodium hypochlorite is not stable as a solid chemical. Corrosion of common alloys in dry chlorine cl2 penflex. Both of type 304 and type 316 stainless steels showed quite similar. If the cl is present as hcl you have a problem that 316 wont solve. Although no stainless steel grade is totally immune. What is the maximum chloride in ppm that can be allowed in. Stress corrosion cracking facts and how to reduce the risk. Chlorideassisted stresscorrosion cracking in type 316. Keep in mind that moisture will greatly accelerate attack of any of these materials with the additional danger of scc stress corrosion cracking of stainless steel. If a stainless part is under tensile stress, the pitting mentioned above will deepen, and cracking may take place.